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Titanium(IV) Chloride ReagentPlus®, 99.9%

Titanium(IV) Chloride ReagentPlus®, 99.9%

Code: S208566-200G

In stock

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200G
7550-45-0
TiCl4
189.68
liquid

€210.00 ex VAT

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General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) have been used for the synthesis of nanosized titanium dioxide.

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.

Along with sodium borohydride, it forms an effective reagent for the reduction of:

  • carboxylic acid and acyl chloride to alcohols
  • carboxamides, oximes and lactams to amines
  • sulfoxides to sulfides

Titanium(IV) chloride (TiCl4) has been used as a precursor for the synthesis of Ag-TiO2@polyethylene glycol (PEG) nanoparticles. TiCl4 may also be used as one of the constituents to synthesize TiO2/Al2O3 binary oxide materials and N-(10-oxo-vinylanthracen-9-(10H)-ylidene)cyanamide.

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